翻訳と辞書 Words near each other ・ Bis(chloromethyl) ether ・ Bis(chloromethyl) ketone ・ Bis(chloromethyl)benzene ・ Bis(cyclooctadiene)nickel(0) ・ Bis(cyclooctatetraene)iron ・ Bis(dicyclohexylphosphino)ethane ・ Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0) ・ Bis(pinacolato)diboron ・ Bis(pyridine)iodonium(I) tetrafluoroborate ・ Bis(triethoxysilylpropyl)tetrasulfide ・ Bis(trimethylsilyl)acetamide ・ Bis(trimethylsilyl)acetylene ・ Bis(trimethylsilyl)amine ・ Bis(trimethylsilyl)mercury ・ Bis(trimethylsilyl)sulfide ・ Bis(triphenylphosphine)iminium chloride ・ Bis(triphenylphosphine)nickel chloride ・ Bis(triphenylphosphine)palladium(II) dichloride ・ Bis(triphenylphosphine)platinum chloride ・ Bis-(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate ・ Bis-choline tetrathiomolybdate ・ Bis-gamma-glutamylcystine reductase ・ Bis-HPPP ・ Bis-peptide ・ Bis-quits ・ Bis-TOM ・ Bis-tris methane ・ Bis-tris propane ・ Bisa ・ Bisa Grant Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Bis(triphenylphosphine)iminium chloride ： ウィキペディア英語版 Bis(triphenylphosphine)iminium chloride |Section2= |Section7= |Section8= }} Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula ()Cl, often written ()Cl and abbreviated PPNCl. This colorless salt is a source of the PPN+ cation, which is used to isolate reactive anions. PPN+ is a phosphazene. ==Synthesis and structure== PPNCl is prepared in two steps from triphenylphosphine: :Ph3P + Cl2 → Ph3PCl2 This triphenylphosphine dichloride is related to phosphorus pentachloride. Treatment of this species with hydroxylamine in the presence of Ph3P results in replacement of the P-Cl bonds by P=N bonds: :2 Ph3PCl2 + NH2OH·HCl + Ph3P → Cl + 4HCl + Ph3PO In PPN+ salts, P-N bond lengths are equivalent, 1.58 Å. The cation is bent at the central nitrogen, and has no inversion centre. Its connectivity is indicated by Ph3P=N=PPh3+. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Bis(triphenylphosphine)iminium chloride」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.